本发明提供一种负极材料硅基材料/聚苯胺/石墨烯复合材料的制备方法及其产品和应用，通过给硅基材料包覆导电高分子聚苯胺来实现有机与无机的复合，外表面通过聚电解质修饰包覆氧化石墨烯，随后通过水合肼对氧化石墨烯还原得到硅基材料/聚苯胺/石墨烯复合材料。中间层导电聚合物聚苯胺在机械韧性方面远优于碳材料，能更好的缓冲硅在充放电过程中产生的巨大体积变化。外层石墨烯极大地提高体系的导电性。该材料综合了硅的高比容量、聚苯胺的高韧性和石墨烯的良好导电性等优点，具有优异的循环和倍率性能，在500 mA g‑1的电流密度下，经过200次循环比容量保持在710 mAh g‑1，可广泛应用在车用动力锂电池负极材料领域。
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[ DB ] CONNECT:[ UseTime:0.001450s ] mysql:host=pc-m5epcw1px949b110u.rwlb.rds.aliyuncs.com;port=3306;dbname=yousedb;charset=utf8
[ SQL ] SHOW COLUMNS FROM `tb_para` [ RunTime:0.001957s ]
[ SQL ] SELECT * FROM `tb_para` WHERE `id` = 1 LIMIT 1 [ RunTime:0.001117s ]
[ SQL ] SHOW COLUMNS FROM `tb_tech` [ RunTime:0.001306s ]
[ SQL ] UPDATE `tb_tech` SET `hit`=`hit`+1 WHERE `id` = 330780 [ RunTime:0.001178s ]
[ SQL ] SELECT * FROM `tb_tech` WHERE `id` = 330780 LIMIT 1 [ RunTime:0.001084s ]
[ SQL ] SHOW COLUMNS FROM `tb_admin` [ RunTime:0.001216s ]
[ SQL ] SELECT `realname` FROM `tb_admin` WHERE `id` = 1 LIMIT 1 [ RunTime:0.000819s ]
[ SQL ] SHOW COLUMNS FROM `tb_category` [ RunTime:0.001004s ]
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[ SQL ] SHOW COLUMNS FROM `tb_anchor` [ RunTime:0.000987s ]
[ SQL ] SELECT * FROM `tb_anchor` ORDER BY `id` ASC [ RunTime:0.002557s ]
[ SQL ] SELECT `id`,`title` FROM `tb_tech` WHERE `id` > 330780 AND `check_status` = 1 AND `category_id` = 138 ORDER BY `submit_date` ASC LIMIT 1 [ RunTime:0.008428s ]
[ SQL ] SELECT `id`,`title` FROM `tb_tech` WHERE `id` < 330780 AND `check_status` = 1 AND `category_id` = 138 ORDER BY `submit_date` DESC LIMIT 1 [ RunTime:0.070847s ]
[ SQL ] SHOW COLUMNS FROM `tb_mcc` [ RunTime:0.001055s ]
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[ SQL ] SHOW COLUMNS FROM `tb_industry_report` [ RunTime:0.001029s ]
[ SQL ] SELECT `id`,`cate_aid`,`cate_bid`,`title`,`pic`,`tag`,`price`,`hit`,`mode` FROM `tb_industry_report` [ RunTime:0.001097s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 36 ORDER BY `sortid` ASC [ RunTime:0.000892s ]
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[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 41 ORDER BY `sortid` ASC [ RunTime:0.000789s ]
[ SQL ] SHOW COLUMNS FROM `tb_advert` [ RunTime:0.000981s ]
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