本发明公开了一种双金属磷化物‑炭电催化析氢材料及其制备方法，所述材料为微米级双金属磷化物‑炭(Co2P/Ni2P/C)电催化析氢材料，属于电催化析氢制备领域。其制备：以钴镍基普鲁士蓝类似物Co‑Ni PBA(Prussian blue analogous，PBA)为前驱体，复合一定量的碳素材料得到Co‑Ni PBA/C中间体，低温磷化后制得Co2P/Ni2P/C双金属磷化物复合材料。该电催化材料价格低廉，环境友好，并且合成方法简单方便，在不同pH电解液中皆具有良好的电催化析氢性能，具有广阔的应用前景。
[8]Trying to access array offset on value of type null[/websites/wwwroot/www.china-mcc.com/runtime/temp/d969c9ac11613d3901d9652da6568a9b.php:214]
[8]Trying to access array offset on value of type null[/websites/wwwroot/www.china-mcc.com/runtime/temp/d969c9ac11613d3901d9652da6568a9b.php:218]
[8]Trying to access array offset on value of type null[/websites/wwwroot/www.china-mcc.com/runtime/temp/d969c9ac11613d3901d9652da6568a9b.php:237]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:128]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:147]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:147]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:128]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:147]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:147]
[8]Array to string conversion[/websites/wwwroot/www.china-mcc.com/thinkphp/library/think/Url.php:128]
[ DB ] CONNECT:[ UseTime:0.001157s ] mysql:host=pc-m5epcw1px949b110u.rwlb.rds.aliyuncs.com;port=3306;dbname=yousedb;charset=utf8
[ SQL ] SHOW COLUMNS FROM `tb_para` [ RunTime:0.001874s ]
[ SQL ] SELECT * FROM `tb_para` WHERE `id` = 1 LIMIT 1 [ RunTime:0.001117s ]
[ SQL ] SHOW COLUMNS FROM `tb_tech` [ RunTime:0.001175s ]
[ SQL ] UPDATE `tb_tech` SET `hit`=`hit`+1 WHERE `id` = 356741 [ RunTime:0.001659s ]
[ SQL ] SELECT * FROM `tb_tech` WHERE `id` = 356741 LIMIT 1 [ RunTime:0.000915s ]
[ SQL ] SHOW COLUMNS FROM `tb_admin` [ RunTime:0.000995s ]
[ SQL ] SELECT `realname` FROM `tb_admin` WHERE `id` = 1 LIMIT 1 [ RunTime:0.000660s ]
[ SQL ] SHOW COLUMNS FROM `tb_category` [ RunTime:0.000926s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `id` = 138 LIMIT 1 [ RunTime:0.000689s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `id` = 28 LIMIT 1 [ RunTime:0.000884s ]
[ SQL ] SHOW COLUMNS FROM `tb_anchor` [ RunTime:0.001248s ]
[ SQL ] SELECT * FROM `tb_anchor` ORDER BY `id` ASC [ RunTime:0.002482s ]
[ SQL ] SELECT `id`,`title` FROM `tb_tech` WHERE `id` > 356741 AND `check_status` = 1 AND `category_id` = 138 ORDER BY `submit_date` ASC LIMIT 1 [ RunTime:0.006644s ]
[ SQL ] SELECT `id`,`title` FROM `tb_tech` WHERE `id` < 356741 AND `check_status` = 1 AND `category_id` = 138 ORDER BY `submit_date` DESC LIMIT 1 [ RunTime:0.069777s ]
[ SQL ] select id,title,tag,submit_date from tb_tech where check_status=1 and id<>356741 order by submit_date desc limit 10 [ RunTime:0.004861s ]
[ SQL ] SHOW COLUMNS FROM `tb_mcc` [ RunTime:0.001070s ]
[ SQL ] SELECT * FROM `tb_mcc` WHERE `classify` = 1 [ RunTime:0.000956s ]
[ SQL ] SELECT * FROM `tb_mcc` WHERE `classify` = 2 [ RunTime:0.001091s ]
[ DB ] CONNECT:[ UseTime:0.001329s ] mysql:host=mccbfzy.mysql.polardb.rds.aliyuncs.com;port=3306;dbname=ysscdb;charset=utf8
[ SQL ] SHOW COLUMNS FROM `tb_industry_report` [ RunTime:0.002144s ]
[ SQL ] SELECT `id`,`cate_aid`,`cate_bid`,`title`,`pic`,`tag`,`price`,`hit`,`mode` FROM `tb_industry_report` [ RunTime:0.001203s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 36 ORDER BY `sortid` ASC [ RunTime:0.000972s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 37 ORDER BY `sortid` ASC [ RunTime:0.000966s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 38 ORDER BY `sortid` ASC [ RunTime:0.003515s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 39 ORDER BY `sortid` ASC [ RunTime:0.000955s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 40 ORDER BY `sortid` ASC [ RunTime:0.000946s ]
[ SQL ] SELECT * FROM `tb_category` WHERE `pid` = 41 ORDER BY `sortid` ASC [ RunTime:0.000909s ]
[ SQL ] SHOW COLUMNS FROM `tb_advert` [ RunTime:0.001085s ]
[ SQL ] SELECT * FROM `tb_advert` WHERE `id` = 62 LIMIT 1 [ RunTime:0.000764s ]
[ SQL ] SELECT * FROM `tb_advert` WHERE `id` = 63 LIMIT 1 [ RunTime:0.000818s ]
[ SQL ] SELECT * FROM `tb_advert` WHERE `id` = 64 LIMIT 1 [ RunTime:0.000801s ]
[ SQL ] SELECT * FROM `tb_advert` WHERE `id` = 65 LIMIT 1 [ RunTime:0.000839s ]
975
编辑：管理员
来源：北方有色网
咨询细节
2026年08月06日 ~ 08日 
